/ Home
/ SUBMISSION

/ The BJOC
/ Diamond Open Access
/ Journal Statistics
/ Editorial Board
/ Community
/ Call for papers

/ Latest Articles
/ Most accessed
/ Thematic issues
/ Volumes
/ Authors

/ Alerts

/ TWITTER
/ LINKEDIN
/ Mastodon
/ RSS FEED

Empty search

Article Type

Publication Date Range

Search Tips

This search combines search strings from the content search (i.e. "Full Text", "Author", "Title", "Abstract", or "Keywords") with "Article Type" and "Publication Date Range" using the AND operator.

Search Examples

aromatic	the word “aromatic”
aromatic aldehyde	the word “aromatic” OR “aldehyde”
+aromatic +aldehyde	both words “aromatic” AND “aldehyde”
+aromatic -aldehyde	the word “aromatic” but NOT “aldehyde”
“aromatic aldehyde”	the exact phrase “aromatic aldehyde”
benz*	words which begin with “benz”, such as “benzene” or “benzyl”
benz*yl	words that begin with “benz” and end with “yl”, such as “benzyl” or “benzoyl”
benzyl~	words that are close to the word “benzyl”, such as “benzoyl” (i.e., fuzzy search)

BROWSE
Latest Articles
Most accessed
thematic issues
volumes
authors

BROWSE

Latest Articles Most Accessed Thematic Issues Volumes Authors

Author

3 article(s) from Stevens, Christian V

A chemoselective and continuous synthesis of m-sulfamoylbenzamide analogues

Arno Verlee,
Thomas Heugebaert,
Tom van der Meer,
Pavel I. Kerchev,
Frank Van Breusegem and
Christian V. Stevens

Beilstein J. Org. Chem. 2017, 13, 303–312, doi:10.3762/bjoc.13.33

PDF

Graphical Abstract

Figure 1: m-Sulfamoylbenzamides as Sirtuin 2 inhibitors (SIRT2) or suppressor of polyglutamine aggregation (p...

Jump to Figure 1

Figure 2: Syrris AFRICA system.

Jump to Figure 2

Album

Supp Info

Full Research Paper

Published 16 Feb 2017

Full text

Synthesis and biological evaluation of novel N-α-haloacylated homoserine lactones as quorum sensing modulators

Michail Syrpas,
Ewout Ruysbergh,
Christian V. Stevens,
Norbert De Kimpe and
Sven Mangelinckx

Beilstein J. Org. Chem. 2014, 10, 2539–2549, doi:10.3762/bjoc.10.265

PDF

Graphical Abstract

Figure 1: Structure of N-acyl homoserine lactone (AHL) and putative n→π* interaction. Attenuation of n→π* int...

Jump to Figure 1

Scheme 1: Synthesis of natural AHLs 3a–f.

Jump to Scheme 1

Scheme 2: Synthesis of brominated AHLs 6a-f and iodinated AHLs 8a–f (^#commercially available compound).

Jump to Scheme 2

Scheme 3: Synthesis of chlorinated AHL analogues 11a–f.

Jump to Scheme 3

Figure 2: Normalized fluorescence values for natural AHLs 3a,b and α-haloacylated analogues 6, 8 and 11 teste...

Jump to Figure 2

Figure 3: Proposed models (Chem3D Pro) of N-(2R)- (left) and N-(2S)-chlorohexanoyl-(S)-homoserine lactone (ri...

Jump to Figure 3

Album

Supp Info

Full Research Paper

Published 30 Oct 2014

Full text

Preparation of phosphines through C–P bond formation

Iris Wauters,
Wouter Debrouwer and
Christian V. Stevens

Beilstein J. Org. Chem. 2014, 10, 1064–1096, doi:10.3762/bjoc.10.106

PDF

Graphical Abstract

Scheme 1: Synthesis of P-stereogenic phosphines 5 using menthylphosphinite borane diastereomers 2.

Jump to Scheme 1

Scheme 2: Enantioselective synthesis of chiral phosphines 10 with ephedrine as a chiral auxiliary.

Jump to Scheme 2

Scheme 3: Chlorophosphine boranes 11a as P-chirogenic electrophilic building blocks.

Jump to Scheme 3

Scheme 4: Monoalkylation of phenylphosphine borane 15 with methyl iodide in the presence of Cinchona alkaloid...

Jump to Scheme 4

Scheme 5: Preparation of tetraphosphine borane 19.

Jump to Scheme 5

Scheme 6: Using chiral chlorophosphine-boranes 11b as phosphide borane 20 precursors.

Jump to Scheme 6

Scheme 7: Nickel-catalyzed cross-coupling (dppe = 1,2-bis(diphenylphosphino)ethane).

Jump to Scheme 7

Scheme 8: Pd-catalyzed cross-coupling reaction with organophosphorus stannanes 30.

Jump to Scheme 8

Scheme 9: Copper iodide catalyzed carbon–phosphorus bond formation.

Jump to Scheme 9

Scheme 10: Thermodynamic kinetic resolution as the origin of enantioselectivity in metal-catalyzed asymmetric ...

Jump to Scheme 10

Scheme 11: Ru-catalyzed asymmetric phosphination of benzyl and alkyl chlorides 35 with HPPhMe (36a, PHOX = pho...

Jump to Scheme 11

Scheme 12: Pt-catalyzed asymmetric alkylation of secondary phosphines 36b.

Jump to Scheme 12

Scheme 13: Different adducts 43 can result from hydrophosphination.

Jump to Scheme 13

Scheme 14: Pt-catalyzed asymmetric hydrophosphination.

Jump to Scheme 14

Scheme 15: Intramolecular hydrophosphination of phosphinoalkene 47.

Jump to Scheme 15

Scheme 16: Organocatalytic asymmetric hydrophosphination of α,β-unsaturated aldehydes 59.

Jump to Scheme 16

Scheme 17: Preparation of phosphines using zinc organometallics.

Jump to Scheme 17

Scheme 18: Preparation of alkenylphosphines 71a from alkenylzirconocenes 69 (dtc = N,N-diethyldithiocarbamate,...

Jump to Scheme 18

Scheme 19: S_NAr with P-chiral alkylmethylphosphine boranes 13c.

Jump to Scheme 19

Scheme 20: Synthesis of QuinoxP 74 (TMEDA = tetramethylethylenediamine).

Jump to Scheme 20

Scheme 21: Pd-Mediated couplings of a vinyl triflate 76 with diphenylphosphine borane 13e.

Jump to Scheme 21

Figure 1: Menthone (83) and camphor (84) derived chiral phosphines.

Jump to Figure 1

Scheme 22: Palladium-catalyzed cross-coupling reaction of vinyl tosylates 85 and 87 with diphenylphosphine bor...

Jump to Scheme 22

Scheme 23: Attempt for the enantioselective palladium-catalyzed C–P cross-coupling reaction between an alkenyl...

Jump to Scheme 23

Scheme 24: Enol phosphates 88 as vinylic coupling partners in the palladium-catalyzed C–P cross-coupling react...

Jump to Scheme 24

Scheme 25: Nickel-catalyzed cross-coupling in the presence of zinc (dppe = 1,2-bis(diphenylphosphino)ethane).

Jump to Scheme 25

Scheme 26: Copper-catalyzed coupling of secondary phosphines with vinyl halide 94.

Jump to Scheme 26

Scheme 27: Palladium-catalyzed cross-coupling of aryl iodides 97 with organoheteroatom stannanes 30.

Jump to Scheme 27

Scheme 28: Synthesis of optically active phosphine boranes 100 by cross-coupling with a chiral phosphine boran...

Jump to Scheme 28

Scheme 29: Palladium-catalyzed P–C cross-coupling reactions between primary or secondary phosphines and functi...

Jump to Scheme 29

Scheme 30: Enantioselective synthesis of a P-chirogenic phosphine 108.

Jump to Scheme 30

Scheme 31: Enantioselective arylation of silylphosphine 110 ((R,R)-Et-FerroTANE = 1,1'-bis((2R,4R)-2,4-diethyl...

Jump to Scheme 31

Scheme 32: Nickel-catalyzed arylation of diphenylphosphine 25d.

Jump to Scheme 32

Scheme 33: Nickel-catalyzed synthesis of (R)-BINAP 116 (dppe = 1,2-bis(diphenylphosphino)ethane, DABCO = 1,4-d...

Jump to Scheme 33

Scheme 34: Nickel-catalyzed cross-coupling between aryl bromides 119 and diphenylphosphine (25d) (dppp = 1,3-b...

Jump to Scheme 34

Scheme 35: Stereocontrolled Pd(0)−Cu(I) cocatalyzed aromatic phosphorylation.

Jump to Scheme 35

Scheme 36: Preparation of alkenylphosphines by hydrophosphination of alkynes.

Jump to Scheme 36

Scheme 37: Palladium and nickel-catalyzed addition of P–H to alkynes 125a.

Jump to Scheme 37

Scheme 38: Palladium-catalyzed asymmetric hydrophosphination of an alkyne 128.

Jump to Scheme 38

Scheme 39: Ruthenium catalyzed hydrophosphination of propargyl alcohols 132 (cod = 1,5-cyclooctadiene).

Jump to Scheme 39

Scheme 40: Cobalt-catalyzed hydrophosphination of alkynes 134a (acac = acetylacetone).

Jump to Scheme 40

Scheme 41: Tandem phosphorus–carbon bond formation–oxyfunctionalization of substituted phenylacetylenes 125c (...

Jump to Scheme 41

Scheme 42: Organolanthanide-catalyzed intramolecular hydrophosphination/cyclization of phosphinoalkynes 143.

Jump to Scheme 42

Scheme 43: Hydrophosphination of alkynes 134c catalyzed by ytterbium-imine complexes 145 (hmpa = hexamethylpho...

Jump to Scheme 43

Scheme 44: Calcium-mediated hydrophosphanylation of alkyne 134d.

Jump to Scheme 44

Scheme 45: Formation and substitution of bromophosphine borane 151.

Jump to Scheme 45

Scheme 46: General scheme for a nickel or copper catalyzed cross-coupling reaction.

Jump to Scheme 46

Scheme 47: Copper-catalyzed synthesis of alkynylphosphines 156.

Jump to Scheme 47

Album

Review

Published 09 May 2014

Full text

Other Beilstein-Institut Open Science Activities

/ Help / Support & Contact / Alerts / Privacy Policy / Terms & Conditions / Impressum